MICROSTRUCTURE FEATURES OF THE CALCIUM MANGANITE IN THE CASE OF DIFFERENT PARTIAL OXYGEN PRESSURE

Evgeny Yu. Gerasimov
1. Institute of Catalysis SB RAS Novosibirsk, Russian Federation
2. Novosibirsk State University Novosibirsk, Russian Federation
gerasimov@catalysis.ru
Vladimir I. Zajkovskij
1. Institute of Catalysis SB RAS Novosibirsk, Russian Federation
2. Novosibirsk State University Novosibirsk, Russian Federation
Lubov I. Isupova
1. Institute of Catalysis SB RAS Novosibirsk, Russian Federation
The material was received by the Editorial Board: 17.07.2009
By the transmission electronic microscopy and X-ray powder diffraction influence of various gas environments on the perovskite – like oxides CaMnO3 microstructure synthesized by polymer-salt method was researched. Formation of the vacancy-ordered structures in the [101] direction in the samples participated in catalytic reaction of CH4 oxidation was revealed. Partial disintegration of the solid solutions was fixed at heating the sample in vacuum up to 1 100 °C.

Keywords:
HRTEM, X-Ray powder diffraction, perovskite, microstructure, planar defect.
УДК 548.736.442.6:546.714

MICROSTRUCTURE FEATURES OF THE CALCIUM MANGANITE IN THE CASE OF DIFFERENT PARTIAL OXYGEN PRESSURE
References: Gerasimov E. Yu., Zajkovskij V. I., Isupova L. I., Tsybulya S. V. MICROSTRUCTURE FEATURES OF THE CALCIUM MANGANITE IN THE CASE OF DIFFERENT PARTIAL OXYGEN PRESSURE. Vestnik NSU. Series: Physics. 2009, vol. 4, no. 4. P. 59–64 (in Russ.). DOI: 10.54362/1818-7919-2009-4-4-59-64