- Siberian Journal of Physics
- Archive
- 2017
- Vol 12. No 4
- Chemical, Biological and Medical Physics
SOME ASPECTS OF THE OBSERVATION OF PARAHYDROGEN-INDUCED POLARIZATION IN HYDROGENATION ON IMMOBILIZED RHODIUM COMPLEXES
Ivan V. Skovpin
1. International Tomography Center SB RAS 3A Institutskaya Str., Novosibirsk, 630090, Russian Federation
2. Novosibirsk State University 2 Pirogov Str., Novosibirsk, 630090, Russian Federation
iskovpin@tomo.nsc.ru
Vladimir V. Zhivonitko
1. International Tomography Center SB RAS 3A Institutskaya Str., Novosibirsk, 630090, Russian Federation
2. Novosibirsk State University 2 Pirogov Str., Novosibirsk, 630090, Russian Federation
Igor V. Koptyug
1. International Tomography Center SB RAS 3A Institutskaya Str., Novosibirsk, 630090, Russian Federation
2. Novosibirsk State University 2 Pirogov Str., Novosibirsk, 630090, Russian Federation
The material was received by the Editorial Board: 23.11.2017
The possibility to use catalysts formed during the reduction of immobilized rhodium complexes under «mild» conditions of the hydrogenation reaction was studied in order to obtain a continuous flow of hyperpolarized propane. It was found that the resulting catalysts are more effective in the context of the production of hyperpolarized propane compared to supported metal catalysts prepared by conventional methods. Keywords:
heterogeneous hydrogenation by parahydrogen, hyperpolarization, immobilized complexes, enhancement of NMR signals.
УДК 544.47
SOME ASPECTS OF THE OBSERVATION OF PARAHYDROGEN-INDUCED POLARIZATION IN HYDROGENATION ON IMMOBILIZED RHODIUM COMPLEXES
References: Skovpin I. V., Zhivonitko V. V., Koptyug I. V. SOME ASPECTS OF THE OBSERVATION OF PARAHYDROGEN-INDUCED POLARIZATION IN HYDROGENATION ON IMMOBILIZED RHODIUM COMPLEXES. Siberian Journal of Physics . 2017, vol. 12, no. 4. P. 79–86. (in Russ.). DOI: 10.25205/2541-9447-2017-12-4-79-86